question 5 of 17 > in a particular redox reaction, mno₂ is oxidized to mno₄⁻ and ag⁺ is reduced to ag…

question 5 of 17 > in a particular redox reaction, mno₂ is oxidized to mno₄⁻ and ag⁺ is reduced to ag. complete and balance the equation for this reaction in acidic solution. phases are optional. balanced redox reaction: 2h₂o + mno₂ + ag⁺ → mno₄⁻ + 2e⁻ + 4h⁺ + ag
Answer
Explanation:
Step1: Write half - reactions
Oxidation: $\ce{MnO2 -> MnO4^-}$ Reduction: $\ce{Ag+ -> Ag}$
Step2: Balance atoms other than O and H in oxidation half - reaction
Already balanced for Mn: $\ce{MnO2 -> MnO4^-}$
Step3: Balance O atoms in oxidation half - reaction by adding $\ce{H2O}$
$\ce{MnO2 + 2H2O -> MnO4^-}$
Step4: Balance H atoms in oxidation half - reaction by adding $\ce{H+}$
$\ce{MnO2 + 2H2O -> MnO4^-+ 4H+}$
Step5: Balance charge in oxidation half - reaction by adding electrons
$\ce{MnO2 + 2H2O -> MnO4^-+ 4H+ + 3e^-}$
Step6: Balance charge in reduction half - reaction
$\ce{Ag+ + e^- -> Ag}$
Step7: Multiply half - reactions to equalize electrons
Multiply oxidation half - reaction by 1 and reduction half - reaction by 3. Oxidation: $\ce{MnO2 + 2H2O -> MnO4^-+ 4H+ + 3e^-}$ Reduction: $\ce{3Ag+ + 3e^- -> 3Ag}$
Step8: Add half - reactions
$\ce{MnO2 + 2H2O+3Ag+ -> MnO4^- + 4H+ + 3Ag}$
Answer:
$\ce{MnO2 + 2H2O+3Ag+ -> MnO4^- + 4H+ + 3Ag}$